Polyaromatic ether-keto-sulfones and their synthesis

摘要

Polymers having pendant phenylethynyl groups are obtained by reacting phenylacetylene with a bromine-containing polymer prepared by reacting bis-p-phenoxy-4,4'-(2,2'-dibromodiphenyl)ketone or 2,2'-dibromodiphenyl-4,4'-dicarbonyldichloride with isophthaloyl dichloride and 4,4'-bis-p-phenoxydiphenylsulfone. Because the polymers cure without the evolution of volatiles and have softening points higher than their cure temperatures, they are especially suitable for use in fabricating fiber-reinforced composites.