发明名称 Process for polymerizing olefins and catalysts therefor
摘要 A process for preparing a polymer or copolymer of an olefin having at least 3 carbon atoms which comprises polymerizing or copolymerizing an olefin having at least 3 carbon atoms and containing 0 to 10 mole % of another olefin or diolefin in the presence of a catalyst composed of (i) a solid titanium catalyst component and (ii) an organoaluminum compound; wherein the solid titanium catalyst component is obtained by contacting (1) a magnesium containing copulverization product comprising (A) an aluminum or germanium compound selected from the group consisting of aluminum compounds of the formula AlRnX3-n wherein R is a hydrogen atom, or an alkyl, alkenyl, aryl, alkoxy, aryloxy or acyloxy group optionally having a substituent, X is a halogen atom, and O<n</=3, and germanium compounds of the formula GeRmX4-m wherein R and X are as defined above, and 0</=m</=4, (B) a halogen-containing magnesium compound, and (C) an organic acid ester, the compounds (A) and (B), or the compounds (A), (B) and (C) being mechanically copulverized, with (2) a titanium compound (D) in the liquid phase in the absence of mechanical pulverization.
申请公布号 US4250285(A) 申请公布日期 1981.02.10
申请号 US19780902946 申请日期 1978.05.04
申请人 MITSUI PETROCHEMICAL INDUSTRIES LTD 发明人 KASHIWA, NORIO;MINAMI, SYUJI;TOYOTA, AKINORI
分类号 C08F4/00;C08F4/02;C08F4/60;C08F4/64;C08F10/04;(IPC1-7):C08F4/02;C08F10/06 主分类号 C08F4/00
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