发明名称 Process for the preparation of aryloxyacetic acid
摘要 In a process for the preparation of an aryloxyacetic acid by oxidation of aryloxyethanol of the formula <IMAGE> (I) wherein m represents 1 or 2, n represents the numeral which results from the difference (6-m) and R either individually or independently of one another represent hydrogen, alkyl, cycloalkyl, aryl, aralkyl, alkoxy, cycloalkoxy, aryloxy, hydroxyl, halogen, alkylcarbonyl, arylcarbonyl, carboxyl or nitro, or represent a benzene ring or cycloalkane ring fused to the phenyl ring, with oxygen or an oxygen-containing gas in an aqueous alkaline medium at a temperature from 0 DEG C. to the boiling point of the reaction mixture in the presence of platinum metals and/or palladium metals containing catalyst, the improvement which comprises carrying out the oxidation in the additional presence of an activator of lead and/or bismuth and/or a compound thereof and optionally in the additional presence of Cadmium and/or its compounds.
申请公布号 US4238625(A) 申请公布日期 1980.12.09
申请号 US19790092783 申请日期 1979.11.08
申请人 BAYER AG 发明人 FIEGE, HELMUT;WEDEMEYER, KARLFRIED
分类号 C07C59/125;B01J23/00;B01J27/00;B01J31/00;C07B61/00;C07C51/00;C07C51/235;C07C51/255;C07C59/70;C07C65/21;C07C67/00;C07C201/00;C07C205/37;(IPC1-7):C07C51/16 主分类号 C07C59/125
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