Process for recovery of chemicals from pulping waste liquor

摘要

A process for recovery of chemicals from a sodium sulfite pulping waste liquor is disclosed in which a smelt obtained from the waste liquor is introduced into an aqueous slurry containing solidified smelt while make up water and a weak aqueous slurry are supplied to effect incomplete dissolution of the smelt into the aqueous slurry to maintain the content of total solid and the temperature of the slurry at constant levels, the resulting aqueous slurry is subjected to a solid-liquid separation to obtain a wet cake having the molar ratio of S/Na2O substantially equal to that of the smelt, the wet cake is mixed with hot particles of sodium carbonate and sodium sulfite while hot air is supplied to effect oxidation of sodium sulfide in the wet cake to sodium sulfite and then the oxidized product is dissolved in aqueous medium and sulfur dioxide-containing gas, preferably the exhaust gas from the recovery boiler, is contacted with the resulting aqueous solution to convert sodium carbonate into sodium sulfite, whereby the overall process is carried out in a closed system and the sulfur component and the sodium component present in the waste cooking liquor are recovered and regenerated into a cooking liquor.