发明名称 Ligated transition metal derivatives of heteropolyanions
摘要 Salts and acids containing a triheteropolyanion in which one addenda atom of a heterododecatungstate or heterododecamolybdate is replaced by one tin atom or by two germanium atoms, in which the tin atom or the germanium atoms are bonded to a ligated transition metal, have outstanding utility as catalysts for the oligomerization of terephthalic acid with ethylene glycol, and for the isomerization of 1-butene, and for the dehydration of 2-butanol and subsequent isomerization of the 1-butene formed.
申请公布号 US4196136(A) 申请公布日期 1980.04.01
申请号 US19780957691 申请日期 1978.11.06
申请人 DU PONT DE NEMOURS, E I & 发明人 KNOTH, WALTER H JR
分类号 B01J31/16;B01J31/22;C07C1/24;C07C5/25;C07F11/00;(IPC1-7):C07F7/22 主分类号 B01J31/16
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