发明名称 Process for the preparation of 4-stilbenyl-1,2,3-triazoles
摘要 The novel triazoles have the formula (I) <IMAGE> in which the symbols A, X, Z and n have the meaning given in Patent Claim 1 and R represents hydrogen or an optionally substituted alkyl group as in Patent Claim 6. The compounds of the formula (I) are prepared by reaction of compounds of the formula (II) <IMAGE> with a mol of sodium azide, where a denotes 1 or 2 and Ar denotes optionally substituted phenyl. If a=1, then R<1> denotes the radical (X)n-A-CH=CH-C6H4- and if a=2, then R<1> denotes a stilbene, distyrylbenzene or distyryldiphenyl radical as a bridge member having two free valencies in the p,p'-position. Alkylation can be carried out after the reaction. The compounds of the formula (I) are suitable as optical brighteners.
申请公布号 CH616414(A5) 申请公布日期 1980.03.31
申请号 CH19750012798 申请日期 1975.10.02
申请人 HOECHST AG 发明人 DR. DIETER GUENTHER;DR. RUEDIGER ERCKEL;DR. ERICH SCHINZEL;GUENTHER ROESCH
分类号 C07D235/06;C07D249/06;C07D263/56;C07D263/57;C07D413/10;C07F9/653;(IPC1-7):C07D249/06;C08K5/34 主分类号 C07D235/06
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