WERKWIJZE VOOR HET BEREIDEN VAN PEROXYDICARBONATEN.

摘要

A peroxydicarbonate represented by the formula R-OCO-OO-OCO-R, wherein R is an organic radical derived from a C1-18 monohydric alcohol is obtained by reacting, at a temperature of from -10 DEG C to 30 DEG C, a chloroformate of the formula R-OCO-Cl with an aqueous solution of hydrogen peroxide containing from 10 to 35 percent by weight of hydrogen perioxide and with an aqueous solution of alkali metal hydroxide containing 20 to 40 percent by weight of the hydroxide, sufficient of each of the peroxide and the hydroxide solutions being used to provide at least a 4 percent stoichiometric excess of the peroxide and at least a 1 percent stoichiometric excess of the hydroxide.