摘要 |
<p>Stilbene cpds. of formula (I): are used as optical brightening agents for high molecular organic materials other than textiles. In (I), X is phenyl, naphthyl or a 4-biphenyl go. R1 is H 1-4C alkyl, 1-4C alkoxy, Cl, cyclohexyl, benzyl, alpha, alpha-dimethylbenzyl, 1-4C alkylsuphonyl, 2-5C carbalkoxy, carboxy, opt. substd. carbamoyl, sulpho or opt. substd. sulphamoyl, or together with R2 forms a trimethylene gp. in the 5,6-position of the benzoxazole ring or, if X is phenyl, R1 and R2 together may form a 1,3-butadienylene gp. in the 4,5-position of the benzoxazole ring system, R2 is H, 1-4C alkyl, 1-4C alkoxy or Cl or together with R1 may form the gps. described above. R3 is H or, if X is phenyl, R3 may also be 1-4C alkyl, 1-4C alkoxy, Cl carboxy, 2-5C carbalkoxy, CN or R3 and R4 together may form a methylenedioxy-, trimethylene or tetramethylene gp. R4 is H or if X is phenyl, R4 may also be 1-4C alkyl, 1-4C alkoxy, Cl or R4 and R3 together may form the gps. described above, and R5 is H, Cl or sulpho gp. The (I) esp. for addn. to wash baths used e.g. with polyamide and cellulosic materials.</p> |