发明名称 MANUFACTURE OF HYDRAZINES
摘要 1. Process for the preparation of hydrazines of the general formula see diagramm : EP0002721,P6,F1 wherein R denotes an aryl or aralkyl radical and R1 denotes an alkyl, aryl or aralkyl radical, or, if R represents an aryl radical R1 can also represent an alkylene or cycloalkylene radical which is bonded to R in the ortho-position relative to the nitrogen, characterized in that secondary amines of the general formula see diagramm : EP0002721,P6,F2 are reacted to give nitrosamines and these are reduced, without being isolated, with zinc dust in the presence of hydrochloric acid or sulphuric acid at 0 to 50 degrees C and at pH values of 5 to 6, and the reduction is brought to completion at pH values of less than 4.
申请公布号 JPS5490127(A) 申请公布日期 1979.07.17
申请号 JP19780157732 申请日期 1978.12.22
申请人 BAYER AG 发明人 ROTAARU NOFUTSU
分类号 B01J23/00;C07C67/00;C07C241/00;C07C243/18;C07C243/22;C07D209/08;C07D209/40;C07D209/82 主分类号 B01J23/00
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