| 摘要 |
A method is disclosed for preparing tertiary olefins starting from the corresponding tertiary ethers, the improvement consisting in contacting the ether with a catalyst composed by active alumina modified by reaction with a silicon compound selected among those corresponding to the general formula: <IMAGE> wherein X,Y,Z and W can be -R, -OR, -Cl, -Br, -SiH3 , -COOR, -SihnOm, R being hydrogen, an alkyl, cycloalkyl, aryl, aralkyl or alkyl-cycloalkyl radical of from 1 to 30 carbon atoms, n and m being integers comprised between 1 and 3. The advantages afforded by the invention are mainly the nearly quantitative yields and the high purity of the end products. |
