发明名称 |
PROCESS FOR THE CONTINUOUS PRODUCTION OF 2-ETHYL HEXANOL |
摘要 |
<p>PROCESS FOR THE CONTINUOUS PRODUCTION OF 2-ETHYL HEXANOL An improvement in a process for preparing 2-ethyl hexanol wherein: A) One mole of n-butyraldehyde is condensed with another mole of n-butyraldehyde in a condensation zone in the presence of an alkali metal hydroxide wherein there is . formed 2-ethyl hexenal and higher condensation products; B) The resultant product is contacted with water to separate alkali metal salts therefrom, an organic phase comprising 2-ethyl hexenal and higher condensation products is separated therefrom and unused alkali metal hydroxide is recycled to the condensation zone; C) The organic phase is separated in a separation zone into a 2-ethyl hexenal rich fraction and a residual fraction having a major amount of higher condensation product; D) The 2-ethyl hexenal rich fraction is introduced into a hydrogenation zone containing hydrogen and a hydrogenation catalyst and therein hydrogenated to 2-ethyl hexanol, the improvement residing in recycling to the condensation zone at least a portion of the residual fraction containing the major amount of higher condensation product.</p> |
申请公布号 |
CA1057313(A) |
申请公布日期 |
1979.06.26 |
申请号 |
CA19750232598 |
申请日期 |
1975.07.31 |
申请人 |
RUHRCHEMIE AKTIENGESELLSCHAFT |
发明人 |
KESSEN, GUNTHER;MEIS, JOSEF |
分类号 |
C07C29/14;C07C27/00;C07C29/141;C07C29/17;C07C31/125;C07C45/74;C07C67/00;(IPC1-7):07C31/02 |
主分类号 |
C07C29/14 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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