| 摘要 |
Reversible alkali metal anode/metal chalcogenide cathode cells, e.g. lithium batteries, are described having electrolyte compositions which consist essentially of (a) organic solvents selected from the group consisting of inertly substituted and unsubstituted ethers, esters, sulfones, organic sulfites, organic sulfates, organic nitrites and organic nitro compounds; and (b) electrolytically active alkali metal salts including polyaryl metallic alkali metal salts having the formula ZMRn wherein Z is an alkali metal, M is a metal selected from the group consisting of Zn, Cd, B, Al, Ga, In, Tl, Sn (stannous), P and As, the Rs are certain aryl radicals, and n is a numerical value equal to one plus the valence of the metal M. Rechargeable, high energy density electrochemical cells containing an anode having an alkali metal as its active material, a cathode having as its active material a transition metal chalcogenide, e.g. TiS2, and an electrolyte composition of the above-described type, are preferred. |
