发明名称 |
Preparation of oxydicarboxylic acid salts |
摘要 |
Oxyethylene dicarboxylic acid alkali metal salts are prepared from the corresponding oxydiethylene or polyoxyethylene diol and an aqueous alkali metal hydroxide in the presence of a catalytically effective amount of a nickel-copper-chromia catalyst at temperatures from about 200 to 300 DEG C. and pressures sufficient to maintain the reactants and products substantially in liquid phase. Preferably, the disodium salt of oxydiacetic acid is prepared by the oxidation of diethylene glycol with an aqueous sodium hydroxide solution in the presence of a catalytically effective amount of the nickel-copper-chromia catalyst. The disodium oxydiacetate can be readily precipitated from the crude reaction mixture by addition of a mixture of methoanol-isopropanol with subsequent filtration.
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申请公布号 |
US4110371(A) |
申请公布日期 |
1978.08.29 |
申请号 |
US19770806981 |
申请日期 |
1977.06.16 |
申请人 |
TEXACO DEVELOPMENT CORPORATION |
发明人 |
SCHULZE, HEINZ;MARQUIS, EDWARD T. |
分类号 |
C07C51/295;C07C59/305;(IPC1-7):C07C59/12 |
主分类号 |
C07C51/295 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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