发明名称 |
PROCESS FOR THE PREPARATION OF MIXED ISOMERIC METHYLENE-BRIDGED POLYCYCLOHEXYL-POLYAMINES |
摘要 |
<p>A process is described for the preparation of mixed isomeric methylene-bridged polycyclohexylpolyamines wherein a mixed isomeric methylene-bridged polyphenyl polyamine mixture having a functionality of from about 2.0 to about 3.3 is pretreated by contacting the mixture and hydrogen with a nickel-containing hydrogenation catalyst at a temperature of from about 25.degree.C. to about 250.degree.C. under a pressure of about 500 to about 15,000 psig. The pretreated isomeric polyamine is then hydrogenated in the presence of ammonia under conventional hydrogenation conditions employing a ruthenium-containing hydrogenation catalyst. The pretreatment step allows the utilization of mixed isomeric methylene-bridged polyphenyl polyamine feed mixtures for the production of isomeric methylene-bridged polycyclohexylpolyamines in high yields without attendant deactivation of the ruthenium hydrogenation catalyst heretofore observed. The process is particularly applicable to continuous operation.</p> |
申请公布号 |
CA1037495(A) |
申请公布日期 |
1978.08.29 |
申请号 |
CA19750220600 |
申请日期 |
1975.02.21 |
申请人 |
TEXACO DEVELOPMENT CORPORATION |
发明人 |
BRENNAN, MICHAEL E.;YEAKEY, ERNEST L. |
分类号 |
C07C209/72;(IPC1-7):07C85/18 |
主分类号 |
C07C209/72 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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