摘要 |
Basic fused cast refractory with principal crystal phases of periclase and magnesium-spinel is made by adding nonfused oxidic inorganic grog particles to molten mass of the refractory as it is cast into a mold cavity, thereby resulting in increased modulus of rupture at temperature in the range of about 1340 DEG -1500 DEG C. and avoidance of shell formation. Molten mass has a composition consisting essentially (by weight) of 45-78% MgO, 0-30% Cr2O3, 0-35% Al2O3, 0-17% FeO + Fe2O3, at least 82% MgO + Cr2O3 + Al2O3 + FeO + Fe2O3, 1-8% SiO2, 0-2% CaO + BaO + SrO2, 0-10% TiO2 and 0-3% fluorine. Nonfused particles have a loss on ignition at 1000 DEG C. of less than about 0.5% by weight and an aggregate SiO2 content at least about equal to the SiO2 content of the molten mass forming the cast refractory. Grog particles are of a size (e.g., within the range of particles passing about 25 mm. sieve openings and retained by about 0.5 mm sieve openings) and in an amount (e.g., about 2.5 to 70% by weight of the cast refractory) sufficient to effect at least partial melting of and penetration into the particles by and resolidification with the cast molten mass so as to form a continuous coherent crystal structure throughout the solidified cast mass wherein discrete grog particles and remnants thereof (if any exist) are not optically identifiable.
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