METHOD OF FINISHING SYNTHETIC ORGANIC FIBROUS MATERIAL IN PARTICULAR OF PROVIDING IT WITH AN ANTISTATIC FINISH

摘要

1508370 Organic compounds; phosphonate esters containing amido groups CIBA-GEIGY AG 18 Dec 1975 [20 Dec 1974(3)] 51869/75 Headings C2C and C2P [Also in Divisions C3 and D1] Compounds of formula (RO) 2 PO.CH 2 CH 2 - CONHCH 2 NHCOCR 1 =CH 2 where R is C 1-8 alkyl and R 1 is H or methyl may be prepared by reacting (meth)acrylamide with a N-methylol #-dialkoxyphosphonopropionamide. Examples describe the preparation of (101a and b) N- (meth)acrylamidomethyl # - dimethoxyphosphonopropionamide, (102 and 103) N-(meth)- acrylamidomethyl # - diisopropoxyphosphanopropionamide and (104) N - acrylamidomethyl #-diethoxyphosphonopropionamide. N - diethoxyphosphonomethyl acrylamide (105) is prepared by reacting methylolacrylamide with triethylphosphite. Compounds of formula (RO) 2 PO.CH 2 CH 2 - CONHCH 2 NR1R11 where R is C 1-8 alkyl, R1 is C 1-24 alkyl and R11 is H or C 1-24 alkyl may be prepared by reacting N-methylol #-dialkoxyphosphonopropionamide with HNR1R11. Examples describe the preparation of (109) N-cetylaminomethyl-, (110) N-stearylaminomethyl-, (111) N-laurylaminomethyl- and (112) N - di - 2 - ethylhexylaminomethyl - # - dimethoxyphosphanopropionamide and (113) N- stearylaminomethyl-, (114) N-hexadecylaminomethyl- and (115) N-distearylaminomethyl #- diisopropoxyphosphonopropionamide. N - dihydroxyethylaminomethyl methacrylamide (106) is prepared by reacting methacrylamide, para - formaldehyde and diethanolamine. 1 - o - methylbenzyl - 2 - hydroxyethyl methacrylate (107) is prepared by reacting 2- glycidyltoluene with methacrylic acid. 2 - hydroxy - 3 - p - phenylsulphonylphenoxyhydroxy propyl methacrylate (108) is prepared by reacting phenyl sulphonyl phenol with glycidyl methacrylate. N - Alkylaminomethyl succinimides, phthalimides and lactams may be prepared by reacting succinimide, phthalimide or a lactam with formaldehyde and an alkylamine. Examples describe the preparation of (116) N-laurylaminomethyl-, (117) N - cetylaminomethyl- and (120) N - distearylaminomethyl phthalimide; (118) N - dilaurylaminomethyl-, (119) N - laurylaminomethyl- and (121) N - cetylaminomethyl - caprolactam; (122) N - laurylaminomethyl- and (123) N - cetylaminomethylsuccinimide; and (124) N-laurylaminomethyllaurinolactam.