发明名称 |
FREMGANGSM}TE FOR FREMSTILLING AV DIACETYLDERIVATET AV P-METOKSYFENYLACETALDEHYD. |
摘要 |
1398175 Aromatic aldehydes SNAMPROGETTI SpA 17 Nov 1972 [26 Nov 1971] 53371/72 Heading C2C Aromatic aldehydes or esterified or acetalized derivatives thereof are produced by a process which comprises subjecting an aromatic olefin having the formula Ar-(CH 2 ) n -CH=CH 2 wherein Ar is an aromatic group and n is 0 or an integer from 1 to 8, to mild oxidation with a salt of Pd in the oxidation state II or with a salt of a metal in an oxidation state isoelectronic with Pd<SP>II</SP> in an anhydrous medium and in the presence of ions of the formula AcO- or RO- wherein Ac is an acyl group and R is an alkyl radical having from 1 to 8 carbon atoms. Examples of metals isoelectronic with Pd<SP>II</SP> are Tl<SP>III</SP> and Pb<SP>IV</SP>. The aldehyde or its derivative may be connected to produce an aromatic amino acid by the Strecker reaction. |
申请公布号 |
NO136974(B) |
申请公布日期 |
1977.08.29 |
申请号 |
NO19720004313 |
申请日期 |
1972.11.24 |
申请人 |
SNAM PROGETTI S.P.A., |
发明人 |
NATTA, GIUSEPPE,;PASQUON, ITALO, |
分类号 |
C07C;C07C43/30;C07C47/52;C07C67/00;C07C69/16;C07D |
主分类号 |
C07C |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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