摘要 |
Hydraulic fluids and lubricants comprise compounds of the formula <FORM:1124354/C4-C5/1> where T is an alkylene radical of 1 to 4 carbon atoms, Y is an alkyl radical of 1 to 4 carbon atoms, R is either a radical of formula A-CF2(CF2)m(CH2)n-, where A is hydrogen or fluorine, m is 0 to 7, n is 1 to 4, or a perfluoroalkylphenyl radical of 7 to 10 carbon atoms, and R1 has the same values as R, or is a hydrocarbon radical containing an aromatic nucleus, which is free of olefinic or acetylenic unsaturation, and contains 6 to 12 carbon atoms. Mixtures of these fluids with known hydraulic fluids, e.g. trialkyl-phosphates, dialkyl aryl phosphonates, or aromatic ethers, or with conventional fluid additives, e.g. corrosion inhibitors, antioxidants, or viscosity-index improvers, may be used. In the examples, the fluids are evaluated in terms of pour point, kinematic viscosity, flash point, fire point, autogenous ignition temperature, and flammability at 1300 DEG F.ALSO:The invention comprises compounds of the formula <FORM:1124354/C2/1> where T is an alkylene radical of 1 to 4 carbon atoms, Y is an alkyl radical of 1 to 4 carbon atoms, R is either a radical of formula A-CF2(CF2)m(CH2)n-where A is hydrogen or fluorine, m is 0 to 7, and n is 1 to 4, or a perfluoralkylphenyl radical of 7 to 10 carbon atoms, and R1 has the same values as R or is a hydrocarbon radical containing an aromatic nucleus, which is free of olefinic or acetylenic unsaturation, and contains 6 to 12 carbon atoms. They may be prepared by reacting a phosphorohalidate of formula <FORM:1124354/C2/2> with an (alkylamino) alkanenitrile of formula <FORM:1124354/C2/3> where X is chlorine, bromine, or iodine. A large number of suitable phosphorohalidates and aminonitriles are specified. In the examples, 3-(methylamino) propionitrile is reacted with (1) bis-(m-trifluoromethylphenyl) phosphorochloridate, (2) bis - (2,2,3,3,4,4,5,5-octafluoropentyl) phosphorochloridate, (3) bis - (2,2,3,3,4,4-heptafluorobutyl) phosphorochloridate, (4)2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoroheptyl phenyl phosphorochloridate, and (5) 2,2,3,3,4,4, 5,5,6,6,7,7 - dodecafluoroheptyl - m - trifluoromethyl phenyl phosphorochloridate. The compounds are useful as hydraulic fluids. |