| 摘要 |
Described herein are melt-processable, solvent resistant polymers comprised of repeating units of formula <IMAGE> having a tensile elongation to break of at least about 50% at room temperature and mean inherent viscosity within the range from about 0.8 to about 1.65. The polymers, which are suitable for high temperature resistant wire insulation, are prepared, e.g., by the hydrogen fluoride-boron trifluoride catalyzed polymerization of a p-phenoxybenzoyl moiety-containing monomer (e.g., p-phenoxybenzoyl halide, p-phenoxybenzoic acid, or C1-C3 alkyl p-phenoxybenzoates) in the presence of a capping agent whose reactivity to acetylation is greater than about 150 relative to benzene reactivity of 1. Wet workup and spray drying techniques are described, the latter preferably including dilution of hydrogen fluoride with liquid SO2, either before or after polymerization.
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