发明名称 COPOLYMERS OF 2-PHENYL ALLYL ALCOHOL AND BUTADIENE, TERPOLYMERS THEREOF WITH STYRENE, AND THEIR PREPARATION
摘要 Copolymers are obtained consisting essentially of 2-phenyl allyl alcohol and butadiene in molar ratio of about 1:1 to 1:22, the major portion of the butadiene in the copolymer having the trans-1-4-structure. Terpolymers are obtained consisting essentially of 2-phenyl allyl alcohol, butadiene and styrene in molar ratios of about 1:2-3:1-4. The copolymers vary from viscous oily copolymers to firm, rubbery copolymers. The terpolymers are rubbery and can be used as synthetic rubbers. The copolymers are useful to prepare crosslinkable coatings, plasticizers and adhesives. High yields, often quantitative, of the copolymers are obtained with an azo catalyst. Water soluble persulfate catalysts and azo catalysts in aqueous medium give good yields of the terpolymers.
申请公布号 US3687914(A) 申请公布日期 1972.08.29
申请号 USD3687914 申请日期 1969.01.06
申请人 ATLANTIC RICHFIELD CO. 发明人 MARC O. THIENOT;JOSEPH A. VERDOL
分类号 C08F16/02;C08F236/04;(IPC1-7):C08D3/02;C08D1/22 主分类号 C08F16/02
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