发明名称 Maintaining HF solubility in alkylation isobutane recycle
摘要 In an HF alkylation process it has been found that combining olefin-acting reactant with a recycle stream including isobutane and HF upstream of an alkylation reaction zone is not harmful to alkylate product quality except when the HF is in a free state, i.e., the HF concentration is above the HF solubility level of the recycle stream. Soluble HF in the recycle stream is not harmful to alkylate product quality, therefore, in an embodiment, the overhead vapor stream of an isobutane stripper is condensed, cooled to a separation temperature, and separated into an HF phase and a hydrocarbon phase, a portion of which is withdrawn as an acid saturated recycle stream including isobutane and entrained acid, and heated to a temperature sufficient to place in solution the entrained acid prior to combination of the acid saturated recycle stream with the olefin-acting reactants.
申请公布号 US4010218(A) 申请公布日期 1977.03.01
申请号 US19750633329 申请日期 1975.11.19
申请人 UOP INC. 发明人 SOBEL, JAY E.
分类号 C07C2/62;(IPC1-7):C07C3/54 主分类号 C07C2/62
代理机构 代理人
主权项
地址