发明名称 |
Metallocene catalyst for the (CO)polymerization of alpha -olefins |
摘要 |
A catalyst active in the (co)polymerization of alpha -olefins is obtained by putting the following components in contact with each other: (i) a "bridged" bis-metallocene derivative of a metal M selected from titanium, zirconium or hafnium, wherein the divalent "bridge" has a rigid structure linked to two eta 5-cyclopentadienyl ring with two methylene groups having a distance from each other of less than 3.5 ANGSTROM ; (ii) a co-catalyst consisting of an organic derivative of a metal M' selected from boron, aluminium, gallium and tin. Such a catalyst allows high polymerization rates to be reached and is particularly suitable for high temperature polymerization process and co-polymerization of ethylene with other alpha -olefins.
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申请公布号 |
US5753578(A) |
申请公布日期 |
1998.05.19 |
申请号 |
US19960667622 |
申请日期 |
1996.06.21 |
申请人 |
ENICHEM S.P.A. |
发明人 |
SANTI, ROBERTO;BORSOTTI, GIAMPIERO;PROTO, ANTONIO;GILA, LILIANA;BUJADOUX, KAREL |
分类号 |
C07C13/38;C07C1/32;C07F17/00;C08F4/60;C08F4/64;C08F4/642;C08F4/659;C08F4/6592;C08F10/00;(IPC1-7):C08F4/64 |
主分类号 |
C07C13/38 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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