发明名称 ALPHA-OLEFIN-ALKENYLSILANE COPOLYMER AND PRODUCTION THEREOF
摘要 PURPOSE:To obtain the subject copolymer having excellent rigidity, transparency and heat resistance by copolymerizing an alpha-olefin and an alkenylsilane using a catalyst comprising a transition metal compound containing cyclopentadiene (derivative) as a ligand and an aluminoxane. CONSTITUTION:A 3-25C alpha-olefin (e.g. propylene) is copolymerized with an alkenylsilane (e.g., trimethylallylsilane) using a catalyst composed of a transition metal compound containing cyclopentadiene or a derivative thereof [e.g. ethylene bis(4,5,6,7-tetrahydroinderlyl) zirconium dichloride] and an aluminoxane (e.g. methylaluminoxane) to afford the aimed copolymer having stereoregular alpha-olefin chains, 0.01-50wt.% content of an alkenylsilane unit and >=0.01 intrinsic viscosity determined at 135 deg.C in a tetralin solution.
申请公布号 JPH03231905(A) 申请公布日期 1991.10.15
申请号 JP19900295228 申请日期 1990.11.02
申请人 MITSUI TOATSU CHEM INC 发明人 ASANUMA TADASHI;KAWANISHI KAORU
分类号 C08F210/00;C08F4/60;C08F4/642;C08F4/6592;C08F30/08;C08F210/04;C08F210/06;C08F210/08;C08F210/14;C08F230/08 主分类号 C08F210/00
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