| 发明名称 | Catalyst and method for hydrogenation of 4,4′-methylenedianiline | ||
| 摘要 | Disclosed is a catalyst for hydrogenation of 4,4′-methylenedianiline (MDA), including a support, a magnesium-aluminum oxide layer covering the support, and a rhodium-ruthenium active layer loaded on the magnesium-aluminum oxide layer, wherein the rhodium and the ruthenium of the rhodium-ruthenium active layer have a weight ratio of 40:60 to 10:90. The hydrogenation catalyst can be collocated with hydrogen for hydrogenation of the MDA to form bis(para-amino cyclohexyl) methane (PACM), and the PACM contains 0 mol % to 25 mol % of (t,t)-isomer. | ||
| 申请公布号 | US9399615(B2) | 申请公布日期 | 2016.07.26 |
| 申请号 | US201514706670 | 申请日期 | 2015.05.07 |
| 申请人 | INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE | 发明人 | Chen Chao-Huang;Lee Chiou-Hwang;Hsu Hsi-Yen |
| 分类号 | C07C209/72;B01J23/58 | 主分类号 | C07C209/72 |
| 代理机构 | Birch, Stewart, Kolasch & Birch, LLP | 代理人 | Birch, Stewart, Kolasch & Birch, LLP |
| 主权项 | 1. A catalyst for hydrogenation of 4,4′-methylenedianiline, comprising: a support, a magnesium-aluminum oxide layer covering the support; and a rhodium-ruthenium active layer loaded on the magnesium-aluminum oxide layer, wherein the rhodium and the ruthenium of the rhodium-ruthenium active layer have a weight ratio of 40:60 to 10:90. | ||
| 地址 | Hsinchu TW | ||