发明名称 |
Emulsion polymerization of vinyl chloride using prehomogenized mixed emulsifier system |
摘要 |
A one-step process for the emulsion polymerization of vinyl chloride using a water-soluble initiator and a prehomogenized aqueous emulsifier system of (1) a C12-C18 straight chain alkyl or alkenyl surfactant and (2) a C16-C20 straight chain alkyl or alkenyl alcohol and/or a straight chain saturated hydrocarbon having a carbon content of greater than 18 is disclosed. Suitable examples of straight chain surfactants include sodium lauryl sulfate and sodium oleate. Suitable alcohols include stearyl alcohol, cetyl alcohol and eicosanol. A suitable hydrocarbon is eicosane. The resulting homo- and copolymer latices have excellent mechanical stabilities, particle sizes generally larger than obtainable using only the mixed surfactant system without prehomogenization of the emulsifier system and good thermal stability.
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申请公布号 |
US4093581(A) |
申请公布日期 |
1978.06.06 |
申请号 |
US19760740989 |
申请日期 |
1976.11.11 |
申请人 |
STAUFFER CHEMICAL COMPANY |
发明人 |
ANDERSON, DONALD F. |
分类号 |
C08F14/00;C08F2/00;C08F2/22;C08F2/26;C08F14/06;(IPC1-7):C08L27/06 |
主分类号 |
C08F14/00 |
代理机构 |
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