| 摘要 |
FIELD: chemistry. ^ SUBSTANCE: present invention pertains to improvement of the method of producing (met)acrylic acid or (met)acrolein using a multi-pipe reactor with a fixed bed. The reactor has several pipes, with at least one catalyst bed in the direction of the axis of the pipe. A heat carrier can regulate temperature outside the flow of the reaction pipe. In the reaction pipes, there is gas-phase catalytic oxidation of at least one type of oxidisable substance, propylene, propane, isobutylene and (met)acrolein by molecular oxygen or a gas, containing molecular oxygen. At the beginning of the process, the difference between the coolant temperature and the peak temperature of the catalyst is set in the interval 20-80°C, and during the process, peak temperature T(°C) of the catalyst in the direction of the axis of the pipe satisfies equation 1, given below: (equation 1), where L, T0, X and X0 stand for length of the reaction pipe, peak temperature of the catalyst in the direction of the axis of the pipe at the beginning of the process, the length up to the position which gives the peak temperature T at the input of the reaction pipe, and the length to the position which gives the peak temperature T0 at the input of the reaction pipe, respectively. ^ EFFECT: method allows for stable output of the target product, with high output for a long period of time, without reduction of catalyst activity. ^ 3 dwg, 2 ex |
