发明名称 Production of terephthalic acid by oxidation of p
摘要 A process for preparing terphthalic acid from p-diahylbenzene or an intermediate oxidation product by reacting them with molecular oxygen or a gas containing molecular oxygen in a 2-4C aliphatic monocarboxylic acid solvent having 2-4C atoms in presence of a heavy metal catalyst. The gas containing molecular oxygen is injected in the lower conical portion of the vertical cylindrical reactor dispersed in the reaction liquid at a distance L from the liquid level by a tube, the reaction materials being supplied at a point near the middle of the reactor at a distance L from the liquid level, the ratio 2/6 being between 1/4 and 1/3, the temperature being controllable between 80 deg. and 150 deg.C and the pressure at a value between 1 and 100 atmospheres.
申请公布号 DE1805884(A1) 申请公布日期 1970.05.27
申请号 DE19681805884 申请日期 1968.10.29
申请人 TEIJIN LTD. 发明人 ICHIKAWA,YATARO;YAMAHITA,GENTARO;AKACHI,YUICHI
分类号 C07C51/265 主分类号 C07C51/265
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