COMPONENTS AND CATALYSTS FOR THE POLYMERIZATION OF OLEFINS

摘要

Disclosed are catalyst components for the polymerization of olefins comprising magnesium halide in active form, and, supported thereon, a titanium halide or titanium halogen alcoholate and an electron-donor compound selected from the diamines of formula (see fig. I) wherein the radicals R1 to R10 are the same or different and are hydrogen or C1-C18 hydrocarbon radicals, with the proviso that at least one of the R7 and R8 radicals and at least one of the R9 and R10 radicals are not hydrogen. Also, disclosed are catalysts obtained from said catalyst components and an Al-alkyl compound, as well as catalysts obtained by reaction of an Al-alkyl compound and a diamine of formula (I) with a solid catalyst component comprising a titanium halide or a titanium halogen alcoholate, and an electron-donor compound having particular characteristics of extractability with Al-triethyl, supported on magnesium halide in active form.