| 摘要 |
1,141,118. Block copolymers. TOYO RAYON K.K. 16 May, 1967 [18 May, 1966; 24 May, 1966], No. 22734/67. Heading C3R. Block copolymers of polyamide and polyester are prepared by heating a solid mixture of polyamide and polyester at a temperature above the second order transition point of the polymer component having the highest second order transition but below the m.p. of the polymer having the lowest m.p. The solid phase reaction may take place at reduced pressure or at atmospheric pressure in an inert gas stream. An intimate mixture of polyamide and polyester is desirable and may be obtained by melt blending the polymers prior to reaction or by dissolving in a solvent and then either distilling off the latter or pouring the resultant solution into a non-solvent liquid. The solid mixture used in the reaction may be a powder or be in the form of chips, pellets or flakes. The polyamide may have M.W. 1000-30,000 and the polyester M.W. 2000-30,000. Although the resultant block copolymers are fibre forming the constituent polyamide and polyester need not be fibre forming. At least 50% of the polyamide terminal groups may be amino or carboxyl and at least 50% of the polyester terminal groups may be hydroxyl. Suitable polyamides are polycapramide, polyhexamethylene adipamide. A suitable polyester is polyethylene terephthalate. Mixing may be achieved by melt blending at 260-320‹ C. for up to 20 minutes; reaction may take place between 150‹ C. and the m.p. of the component having the lowest m.p. Fibres may be obtained by melt spinning. Composite fibres may be obtained by melt-spinning a block copolymer prepared by the process according to the invention with another fibre-forming polymer. |
