发明名称 PROCEDE DE PREPARATION DE NOUVEAUX CATALYSEURS CONTENANT DU RHODIUM
摘要 <p>The present invention refers to the compounds ( mu -hydrazine-N<1>:N<2>)-bis[bis(triphenylphosphine)-chlororhodium (I)] and di( mu -hydrazine-N<1>:N<2>)-bis[bis(triphenylphosphine)rhodium (I)] dichloride, which are homogenous hydrogenation catalysts and their application in the hydrogenation of the exocyclic methylene group of acid addition salts of 6-demethyl-6-deoxy-6-methylene-5-hydroxytetracycline (methacycline) to prepare alpha -6-deoxy-5-hydroxytetracycline (doxycycline).</p>
申请公布号 FR2612802(B1) 申请公布日期 1992.10.02
申请号 FR19880000205 申请日期 1988.01.11
申请人 PLURICHEMIE ANSTALT 发明人 HEGGIE WILLIAM;PAGE PHILIP RONALD;VILLAX IVAN;HURSTHOUSE MICHAEL BARRY;SOMERVILLE RICHARD GERARD
分类号 C07B53/00;B01J31/00;B01J31/16;B01J31/18;B01J31/22;B01J31/24;C07B31/00;C07B61/00;C07C67/00;C07C231/00;C07C231/12;C07C237/26;C07C237/44;(IPC1-7):B01J31/24;B01J31/28;C07F15/00 主分类号 C07B53/00
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