发明名称 DERIVATIVES OF BORANOCARBONATE, METHOD FOR THEIR PREPARING AND APPLYING, SET FOR PREPARING CARBONYL COMPLEXES OF TRANSIENT METALS
摘要 FIELD: chemistry of complex compounds. ^ SUBSTANCE: invention relates to new derivatives of boranocarbonate of the formula (I): wherein X1 means -H; X3 and X2 mean similar or different substitutes that are taken among the group consisting of -H, -NHxRy at x + y = 3, or -R wherein R means substitute that is bound with nitrogen or boron atom through carbon atom, respectively, and represents methyl or ethyl group; Y means group -OH, -OH2, -OR or -NHR wherein R means substitute that is bound with nitrogen or oxygen atom through carbon atom, respectively, and represents methyl or ethyl group; or their salts. Invention provides using prepared compounds as source of carbon monoxide (CO) and as a reducing agent in preparing carbonyl metal complexes in an aqueous solution. Also, invention involves a method for preparing borane carbonate and a method for reducing with using H3BCO as a reducing agent. ^ EFFECT: improved method for preparing. ^ 20 cl, 14 ex
申请公布号 RU2256664(C2) 申请公布日期 2005.07.20
申请号 RU20020106404 申请日期 2000.10.05
申请人 发明人 AL'BERTO RODZHER ARIEL;SHCHIBLI RODZHER
分类号 C01B6/13;C07C303/22;C07C309/42;C07F1/06;C07F5/02;C07F19/00 主分类号 C01B6/13
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