发明名称 DEHYDROGENATION OF AZASTEROIDS
摘要 A process for dehydrogenating a compound of the formula <CHEM> <CHEM> which comprises reacting the compound with a silylating agent in the presence of a quinone to introduce a DELTA <1> double bond. Novel intermediates are compounds of the formula <CHEM> wherein: Q is absent or is <CHEM> where R<4> is methyl, C1-8 straight or branched chain alkyl, C3-6 cycloalkyl, phenyl, or combinations thereof; and R<1><4> is hydrogen, C1-6 alkyl, C1-6 straight or branched chain alkoxy, halo, nitro or cyano.
申请公布号 AU1845788(A) 申请公布日期 1989.01.05
申请号 AU19880018457 申请日期 1988.06.27
申请人 MERCK & CO., INC. 发明人 NAME NOT GIVEN
分类号 C07J51/00;B01J21/06;C07J19/00;C07J63/00;C07J73/00;C07J75/00 主分类号 C07J51/00
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