摘要 |
A novel crystalline zirconium oxide powder has a BET specific surface of less than 30 (pref. 10-20) sq.m./g., a primary particle size of 0.1-0.5 microns, a monoclinic crystal structure and opt. a content of 1-10 wt. % Y2O3 and/or 1-10 wt. % MqO. Prodn. of the powder involves addinq an aq. Zr salt soln., opt. contg. Y and/or Mq ions, with stirrinq to an aq. base soln., e.q. caustic soda with an NaOH excess correspondinq to 0.5 mol/lNaOH, hydrothermally treating the reaction mixt. at 200-400 deg. C, filtering off the resulting product, water washinq free of chloride and drying at 10O-120 deg. C.
|
申请人 |
DEGUSSA AG, 6000 FRANKFURT, DE |
发明人 |
KRIECHBAUM, DR., GANGOLF, W-6463 FREIGERICHT, DE;KLEINSCHMIT, DR., PETER, W-6450 HANAU 9, DE;PEUCKERT, DR., DORIS, W-6238 HOFHEIM/TAUNUS, DE |