摘要 |
1,190,513. Optical brighteners for polymers. J. R. GEIGY A.G. 15 Feb., 1968 [16 Feb., 1967], No. 7485/68. Headings C3P and C3R. Optical brighteners for polymers comprise v-triazolyl coumarins of the general formula where V and W each represent an alkyl, phenyl or phenylalkyl group which may be substituted by non-reactive non-chromogenic substituents, Y represents phenyl which may be similarly substituted, R 1 and R 4 are hydrogen or methyl and R 2 and R 3 are hydrogen, methyl or methoxy. Specified polymers are polyethylene, polypropylene, polyvinyl chloride, polyesters such as polyterephthalic acid glycol esters and polyamides such as nylon 6 and 66. About 0À001 to 0À5% of brightener is used. It is incorporated into the melt before spinning and may be combined with plasticizers, e.g. dioctyl phthalate, stabilizers, e.g. dibutyl tin dilaurate or sodium penta-octyl tripolyphosphate, or pigments, e.g. TiO 2 . It may also be added to the monomers before polymerization.
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