发明名称 USE OF 2,2,6,6 TETRAALKYLPIPERIDINE-N-OXYL RADICALS HAVING LONG ALKYL CHAINS AS POLYMERIZATION REGULATORS
摘要 The present invention relates to a polymerizable composition, comprising a) at least one ethylenically unsaturated monomer or oligomer, b) a radical source capable of starting polymerization of the ethylenically unsaturated monomer or oligomer and c) at least one compound of formula (I), wherein n is 1 or 2; R 3, R4, R9, R10 are each independently of one another C1-C18alkyl, C2-C18alkenyl or C2-C18alkinyl; or R3 and R4 and/or R9 and R10 form together with the linking carbon atom a C3-C12cycloakyl radical; R5, R6, R7, R8 are each independently of one another hydrogen, C1-C18alkyl, C2-C18alkenyl or C2- C18alkinyl; X is -O-, -O-C(O)-, -NR2- or -NR2-C(O)-; R2 is hydrogen, C1- C18alkyl or phenyl; if n is 1, R1 is C8-C36alkyl, C8-C36alkenyl or C8- C36alkinyl; if n is 2, R1 is C10-C36alkylen, C10-C36alkenylen or C10- C36alkinylen. Further objects of the present invention are a process for polymerization and the use of compounds of formula (I) for the polymerizatio n of ethylenically unsaturated monomers.
申请公布号 CA2334563(A1) 申请公布日期 1999.12.29
申请号 CA19992334563 申请日期 1999.06.15
申请人 CIBA SPECIALTY CHEMICALS HOLDING INC. 发明人 ROTH, MICHAEL;FUSO, FRANCESCO;CLAUSS, MARGOT;WUNDERLICH, WIEBKE
分类号 C08F2/02;C08F2/14;C08F2/16;C08F2/38;C08F4/00;(IPC1-7):C08F4/00 主分类号 C08F2/02
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