发明名称 REGENERATION OF A HETEROGENEOUS CATALYST IN ETHENE OLIGOMERIZATION
摘要 The invention relates to the in situ regeneration of heterogeneous oligomerization catalysts which are used in the liquid phase oligomerization of ethene.
申请公布号 US2016257630(A1) 申请公布日期 2016.09.08
申请号 US201615056147 申请日期 2016.02.29
申请人 EVONIK DEGUSSA GMBH 发明人 Stochniol Guido;Peitz Stephan;Maschmeyer Dietrich;Reeker Helene
分类号 C07C2/24;C07C41/06 主分类号 C07C2/24
代理机构 代理人
主权项 1. A process for oligomerizing ethene over a heterogeneous catalyst and for regenerating said catalyst, having the following features: a) the oligomerization is effected in an oligomerization operation in which ethene at least partly dissolved in a liquid solvent is contacted with the heterogeneous catalyst; b) the regeneration is effected in a regeneration operation in which the catalyst in the absence of ethene, hydrogen and oxygen is purged with a liquid purge medium; c) oligomerization operation and regeneration operation alternate over time, such that a time-limited oligomerization operation is followed by a time-limited regeneration operation, and the latter in turn by a time-limited oligomerization operation; d) the heterogeneous catalyst is always at the same location, which is the reason why both oligomerization operation and regeneration operation take place at this location; e) the location of the catalyst is supplied with thermal energy in order to impose a set temperature thereon, it being entirely possible for the actual temperature at the catalyst to deviate from the set temperature in a time- and space-limited manner; f) the set temperature in regeneration operation is higher than the set temperature in oligomerization operation.
地址 Essen DE