发明名称 Solid organic scintillator doped by one or more chemical elements
摘要 The invention relates to a solid organic scintillator comprising a polymeric matrix in which there are dispersed one or more fluorophore compounds and one or more chemical elements having an atomic number ranging from 40 to 83, characterized in that said scintillator has a weight content of said chemical elements of at least 5% by weight relative to the total weight of the scintillator, and in that the scintillator emits an emission spectrum comprising an emission peak at a wavelength of at least 550 nm.
申请公布号 US9499738(B2) 申请公布日期 2016.11.22
申请号 US201113992977 申请日期 2011.12.20
申请人 COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES 发明人 Hamel Matthieu;Darbon Stephane;Normand Stephane;Turk Gregory
分类号 C09K11/06;G21K4/00 主分类号 C09K11/06
代理机构 Hultquist, PLLC 代理人 Hultquist, PLLC ;Grant Mary B.
主权项 1. A solid organic scintillator comprising a polymeric matrix in which are dispersed a first fluorophore compound and a second fluorophore compound and one or more metal methacrylics wherein the metal is selected from the group consisting of Pb and Sn, wherein said scintillator has a weight content of said chemical elements of at least 5% by weight relative to the total weight of the scintillator, and wherein the scintillator emits an emission spectrum comprising an emission peak at a wavelength of at least 550 nm and has a scintillation decay time of less than 20 ns, wherein the first fluorophore compound is according to formula (I):wherein:R1 is a mesomeric donor group;R2 is a hydrogen atom or mesomeric donor group the same or different from R1;R3 is: an acyl group; or a straight-chain or branched, saturated or unsaturated C1 to C20 hydrocarbon group, optionally substituted, or a cyclic saturated C3 to C10 hydrocarbon group, optionally substituted; or a saturated C3 to C10 heterocyclic group, optionally substituted; or an aryl or heteroaryl group, optionally substituted;or one of the salts thereof; and wherein the second fluorophore compound is a perylene-diimide compound according to formula (III):wherein R4, R5, R6, R7, R8 and R9 independently of each other represent a hydrogen atom, an optionally substituted straight-chain or branched, saturated or unsaturated C1 to C20 hydrocarbon group, or an optionally substituted aryl or heteroaryl group.
地址 Paris FR