| 主权项 |
1. A method of repelling a honeybee from a location or a structure or a plant, the method comprising the step of applying a honeybee to the location, the structure, the plant and/or in a vicinity nearby the location, the structure, or the plant, wherein application of the honeybee repellent to the location, the structure or the plant repels a honeybee from the location, the structure, or the plant, wherein the honeybee repellent has a structure of formula XIIIa: wherein X is C, N, O or S; Z is C or N; R1 and R2 are each independently selected from H, C1-6 alkyl, C2-6 alkenyl, C2-6 alkynyl, optionally substituted alkylaryl, optionally substituted arylalkyl, alkoxy, optionally substituted aryloxy, optionally substituted arylalkoxy, optionally substituted alkoxyalkylaryl, alkylamino, aminoalkyl, dialkylamino, optionally substituted arylamino, optionally substituted aminoaryl, heteroalkyl, optionally substituted heteroaryl, optionally substituted heteroarylalkyl, cyclic heteroalkyl, cyclic heteroalkylalkyl, acyl, optionally substituted benzoyl, optionally substituted 2-benzoylethenyl, NH2, NR5R6, OH, OR5, CN, NO2, OCF3, CF3, Br, Cl, F, 1-amidino, 2-amidino, alkylcarbonyl, morpholino, piperidinyl, dioxanyl, pyranyl, optionally substituted heteroaryl, furanyl, thiophenyl, tetrazole, thiazole, isothiazole, imidazole, thiadiazole, thiadiazole S-oxide, thiadiazole S,S-dioxide, sulfonylamidine, sulfonylguanidine, sulfamoylamidine, sulfamoylguanidine, pyrazole, oxazole, isoxazole, pyridinyl, pyrimidinyl, piperazine, quinoline, isoquinoline; R5 is each independently H, OH, C1-6 alkyl, OC1-6 alkyl, CO2C1-6 alkyl, halogen, NO2, or SO2; and m is 0 to 5; and wherein the C1-6 alkyl includes C1-6 cycloalkyl, C2-6 alkenyl includes C2-6 cycloalkenyl, C2-6 alkynyl includes C2-6 cycloalkynyl, OC1-6 alkyl includes OC1-6 cycloalkyl and CO2C1-6 alkyl includes CO2C1-6 cycloalkyl. |
