发明名称 (S)-1-HYDROXY-2,2,2-TRIFLUOROETHYL-TERMINATED ETHOXYALKYL KETONE AND ITS PRODUCTION
摘要 PROBLEM TO BE SOLVED: To obtain the subject new compound useful as an intermediate for antiferroelectric liquid crystal compounds, or as a building blocking agent capable of introducing various functional groups into compounds to be used as medicines or agrochemicals. SOLUTION: This new compound is expressed by the formula (m is 3-6), e.g. (S)-1-hydroxy-2,2,2-trifluoroethyl-4-ethoxybutyl ketone. The compound of the formula is obtained by reaction between (S)-N-(2-hydroxy-3,3,3- trifluoropropionyl)pyrrolidine and a compound of the formula C2 H5 O(CH2 )m MgBr in an organic solvent such as diethyl ether, tetrahydrofuran or diglyme followed by the hydrolysis of the reaction product with a mineral, acid such as hydrochloric acid, sulfuric acid or nitric acid.
申请公布号 JPH0959203(A) 申请公布日期 1997.03.04
申请号 JP19950237744 申请日期 1995.08.23
申请人 TOAGOSEI CO LTD 发明人 KUBOTA TOSHIO;IIJIMA NORIHISA
分类号 G02F1/13;C07C45/42;C07C45/56;C07C49/175;C09K19/20;(IPC1-7):C07C49/175 主分类号 G02F1/13
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