发明名称 Process for producing a polycarbonate copolymer
摘要 A polycarbonate copolymer having a desirable heat resistance and impact resistance, and a process for producing the copolymer. The polycarbonate copolymer comprises a carbonate structural unit of the formula (I): <IMAGE> (I) wherein A is alkylidene, alkylene, arylene, arylalkylene, -O-, -S-, -SO2- or a single bond, and a carbonate structural unit of formula (II): <IMAGE> (II) wherein X1 and Y1 are hydrogen, halogen or an organic group and m and n are 1 to 4, wherein the proportion of the carbonate structural unit of the formula (II) being 2 to 15 mole % based on the amount of the carbonate structural unit of the formulas (I) and (II), and the viscosity average molecular weight of the copolymer being 15,000 to 40,000. The polycarbonate copolymer is produced by an interfacial polycondensation of an aromatic diol and a fluorene compound, with phosgene or a phosgene derivative in the presence of methylene chloride as an inert organic solvent, the fluorene derivative being in the form of aqueous solution in potassium hydroxide.
申请公布号 US5391693(A) 申请公布日期 1995.02.21
申请号 US19930130359 申请日期 1993.10.01
申请人 IDEMITSU PETROCHEMICAL CO., LTD. 发明人 NAKAE, MITSUGU
分类号 C08G64/06;C08G64/24;(IPC1-7):C08G64/00 主分类号 C08G64/06
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