| 摘要 |
FIELD: chemistry. ^ SUBSTANCE: invention relates to organic synthesis, particularly to a method of producing novel organoaluminium compounds which can be used as components of catalyst systems in oligomerisation and polymerisation of olefin, diene and acetylene hydrocarbons, as well as in fine organic and organometallic synthesis. A method is described for producing tricyclo[4.2.1.02.5]nonane-3-spiro(3'-ethyl-3'-aluminacyclopentane) (1), involving reacting 3-methylenetricyclo[4.2.1.02.5]nonane with triethylaluminium in the presence of a zirconocene dichloride catalyst in an argon atmosphere at room temperature in hexane for 8-12 hours. ^ EFFECT: proposed method allows for obtaining novel organoaluminium compounds (1) with high output ranging from 78 to 92%, which can be widely used in the chemical industry. ^ 1 cl, 1 tbl, 7 ex |
