发明名称 |
alpha -olefin polymerization catalyst system and process for producing alpha -olefin catalyst |
摘要 |
An alpha -olefin polymerization catalyst system having so high a catalytic activity and stereoregularity that the catalyst residue and amorphous polymer need not be removed and a process for producing an alpha -olefin polymer using the catalyst system, said catalyst system consisting essentially of: (A) a trivalent titanium compound-containing solid catalyst component prepared by reducing a titanium compound, represented by the general formula Ti(OR1)aX4-a in which R1 represents a hydrocarbon group having 1 to 20 carbon atoms; X represents a halogen atom; and a represents a numeral satisfying 0<a</=4, with an organomagnesium compound in the presence of Si-O bond-containing organosilicon compound and an ester compound (a) to obtain a solid product, treating the solid product with an ester compound (b) to obtain an ester-treated solid product, and treating the ester-treated solid product with a mixture of an ether compound and titanium tetrachloride or a mixture of an ether compound, titanium tetrachloride and an ester compound (c), wherein the ester compounds (a), (b) and (c) may be the same or different from one another; (B) an organoaluminum compound and (C) an electron donative compound.
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申请公布号 |
US5608018(A) |
申请公布日期 |
1997.03.04 |
申请号 |
US19940350158 |
申请日期 |
1994.11.30 |
申请人 |
SUMITOMO CHEMICAL COMPANY, LIMITED |
发明人 |
EBARA, TAKESHI;KIYOTA, TERUYOSI;IMAI, AKIO |
分类号 |
C08F4/654;C08F4/656;C08F10/00;(IPC1-7):C08F4/651 |
主分类号 |
C08F4/654 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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