发明名称 alpha -olefin polymerization catalyst system and process for producing alpha -olefin catalyst
摘要 An alpha -olefin polymerization catalyst system having so high a catalytic activity and stereoregularity that the catalyst residue and amorphous polymer need not be removed and a process for producing an alpha -olefin polymer using the catalyst system, said catalyst system consisting essentially of: (A) a trivalent titanium compound-containing solid catalyst component prepared by reducing a titanium compound, represented by the general formula Ti(OR1)aX4-a in which R1 represents a hydrocarbon group having 1 to 20 carbon atoms; X represents a halogen atom; and a represents a numeral satisfying 0<a</=4, with an organomagnesium compound in the presence of Si-O bond-containing organosilicon compound and an ester compound (a) to obtain a solid product, treating the solid product with an ester compound (b) to obtain an ester-treated solid product, and treating the ester-treated solid product with a mixture of an ether compound and titanium tetrachloride or a mixture of an ether compound, titanium tetrachloride and an ester compound (c), wherein the ester compounds (a), (b) and (c) may be the same or different from one another; (B) an organoaluminum compound and (C) an electron donative compound.
申请公布号 US5608018(A) 申请公布日期 1997.03.04
申请号 US19940350158 申请日期 1994.11.30
申请人 SUMITOMO CHEMICAL COMPANY, LIMITED 发明人 EBARA, TAKESHI;KIYOTA, TERUYOSI;IMAI, AKIO
分类号 C08F4/654;C08F4/656;C08F10/00;(IPC1-7):C08F4/651 主分类号 C08F4/654
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