发明名称 Metal-air cell provided with gel-form solid electrolyte
摘要 There is provided a lithium-air secondary cell having an air electrode, a negative electrode containing metal lithium or a lithium-containing material and a gel-form solid electrolyte, wherein the gel-form solid electrolyte contains a solid electrolyte salt, a solvent, and a specific lipid peptide-type gelator composed.
申请公布号 US9431689(B2) 申请公布日期 2016.08.30
申请号 US201214351729 申请日期 2012.10.12
申请人 NISSAN CHEMICAL INDUSTRIES, LTD.;KYUSHU UNIVERSITY 发明人 Ishihara Tatsumi;Mitsui Shigeru;Miyachi Nobuhide
分类号 H01M4/38;H01M12/08;H01M4/90;H01M4/92 主分类号 H01M4/38
代理机构 Oliff PLC 代理人 Oliff PLC
主权项 1. A lithium-air secondary cell comprising: an air electrode; a negative electrode containing metal lithium or a lithium-containing material; and a gel-form solid electrolyte, wherein the gel-form solid electrolyte contains a solid electrolyte salt, a solvent, and a lipid peptide-type gelator composed of at least one of compounds of Formulae (1) to (3):(where R1 is a C9-23 aliphatic group, R2 is a hydrogen atom or a C1-4 alkyl group optionally having a C1 or C2 branched chain, R3 is a —(CH2)n—X group, n is a number of 1 to 4, and X is an amino group, a guanidino group, a —CONH2 group, a 5-membered ring optionally having 1 to 3 nitrogen atoms, a 6-membered ring optionally having 1 to 3 nitrogen atoms, or a condensed heterocycle that is composed of a 5-membered ring and a 6-membered ring and optionally has 1 to 3 nitrogen atoms),(where R4 is a C9-23 aliphatic group, each of R5 to R7 is independently a hydrogen atom, a C1-4 alkyl group optionally having a C1 or C2 branched chain, or a —(CH2)n—X group, n is a number of 1 to 4, and X is an amino group, a guanidino group, a —CONH2 group, a 5-membered ring optionally having 1 to 3 nitrogen atoms, a 6-membered ring optionally having 1 to 3 nitrogen atoms, or a condensed heterocycle that is composed of a 5-membered ring and a 6-membered ring and optionally has 1 to 3 nitrogen atoms), and(where R8 is a C9-23 aliphatic group, each of R9 to R12 is independently a hydrogen atom, a C1-4 alkyl group optionally having a C1 or C2 branched chain, or a —(CH2)n—X group, n is a number of 1 to 4, and X is an amino group, a guanidino group, a —CONH2 group, a 5-membered ring optionally having 1 to 3 nitrogen atoms, a 6-membered ring optionally having 1 to 3 nitrogen atoms, or a condensed heterocycle that is composed of a 5-membered ring and a 6-membered ring and optionally has 1 to 3 nitrogen atoms), and pharmaceutically acceptable salts of the compounds.
地址 Tokyo JP