发明名称 Electro-fluorescent emitter for ultra-violet OLED
摘要 The present invention demonstrates a newly designed and synthesized carbazole scaffold based electro-fluorescent emitter, 9-butyl-2,7-(2-(4-methoxyphenyl)ethynyl)-9H-carbazole (Cz(APhOMe)2), for ultra-violet OLED. This novel emitter has showed a high quantum yield of ˜78%. By doping in a host light-emitting layer of an OLED, the Cz(APhOMe)2 guest light-emitting material shows a UV light belong to the near-UV region with high external quantum efficiency. Most importantly, a variety of experiment results have proved that this UV light is a pure UV light having only one peak wavelength in the emission spectrum thereof. Ascertainably, this pure UV light can be applied in numerous applications, such as biological sensors chemical sensors, leakage detection in automobiles, crack detection in airplanes, high density information storage devices, water treatment for germicidal protection, forensic investigations, sanitation and sterilization, laboratory researches, food industries, and fraud detection.
申请公布号 US9346756(B2) 申请公布日期 2016.05.24
申请号 US201414522749 申请日期 2014.10.24
申请人 National Tsing Hua University 发明人 Jou Jwo-Huei;Kumar Sudhir;Koil Pitchai Rajapandian Justin Thomas
分类号 C07D209/86;C07D209/90;C09K11/06 主分类号 C07D209/86
代理机构 代理人
主权项 1. An electro-fluorescent emitter for ultra-violet OLED, wherein the electro-fluorescent emitter is a ultra-violet fluorescent emitting material constructed by at least one polycyclic aromatic hydrocarbons (PAHs) and at least one benzene compound through a Sonogashira coupling reaction by using a plurality of catalytic agents comprising Pd(PPh3)2Cl2) (Palladium(II)bis(triphenylphosphine)dichloride), PPh3 (Triphenylphosphine), CuI (Cuprous iodide), and (C2H5)3N (Triethylamine); wherein the chemical structure of the ultra-violet fluorescent emitting material being represented by following formulae 4 or 5:
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