发明名称 |
SOLID ELECTROLYTE, ALL-SOLID-STATE BATTERY INCLUDING THE SAME, AND METHOD FOR MAKING SOLID ELECTROLYTE |
摘要 |
A solid electrolyte comprises a ramsdellite-type crystal structure and has low activation energy of lithium ions and good lithium ion conductivity. The solid electrolyte is represented by the general formula Li4x−2a−3b−c−2dSn4−x−c−dM(II)aM(III)bM(V)cM(VI)dO8 [wherein M(II) is a divalent cation, M(III) is a trivalent cation, M(V) is a pentavalent cation, and M(VI) is a hexavalent cation, 0≦x≦1.33], wherein in the general formula, 0<a+b+c+d, 0≦a+b≦x, 0≦c+d<0.9, and 3x−a−2b−c−2d≦2. The all-solid-state battery includes the solid electrolyte in at least one layer of the positive electrode layer, negative electrode layer, and solid electrolyte layer. The method of making the solid electrolyte includes a step of preparing a mixed powder as a raw material and heating with microwave irradiation. |
申请公布号 |
US2016181657(A1) |
申请公布日期 |
2016.06.23 |
申请号 |
US201514969569 |
申请日期 |
2015.12.15 |
申请人 |
HITACHI, LTD. |
发明人 |
KAWAJI Jun;ASARI Yusuke;FUJIEDA Tadashi;TAKIZAWA Hirotugu;HAYASHI Yamato |
分类号 |
H01M10/0562;H01M10/0585;H01M10/0525 |
主分类号 |
H01M10/0562 |
代理机构 |
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代理人 |
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主权项 |
1. A solid electrolyte having a ramsdellite-type crystal structure, the solid electrolyte being represented by a general formula Li4x−2a−3b−c−2dSn4−x−c−dM(II)aM(III)bM(V)cM(VI)dO8 [wherein M(II) is a divalent cation, M(III) is a trivalent cation, M(V) is a pentavalent cation, and M(VI) is a hexavalent cation, 0≦x≦1.33], wherein in the general formula, 0<a+b+c+d, 0≦a+b≦x, 0≦c+d<0.9, and 3x−a−2b−c−2d≦2. |
地址 |
Tokyo JP |