发明名称 COMPOSITION FOR ADDITION TO ELECTROLYTE SOLUTIONS CONTAINING SILYL GROUP-CONTAINING COMPOUND, ELECTROLYTE SOLUTION FOR NONAQUEOUS ELECTRICITY STORAGE DEVICES CONTAINING SAID COMPOSITION, AND LITHIUM ION SECONDARY BATTERY CONTAINING SAID ELECTROLYTE SOLUTION
摘要 The present invention addresses the problem of providing a composition for addition to electrolyte solutions, which improves storage stability of a silyl group-containing compound that is a useful additive for lithium ion secondary batteries. The description of this application sets forth a composition for addition to electrolyte solutions, which contains one or more silyl group-containing compounds (compound (a)) and one or more basic compounds and/or silicon compounds (compound (b)).
申请公布号 US2016248121(A1) 申请公布日期 2016.08.25
申请号 US201415025837 申请日期 2014.12.05
申请人 ASAHI KASEI KABUSHIKI KAISHA 发明人 UEMATSU Nobuyuki;OZAKI Fumiaki;NAKAMURA Ayaka
分类号 H01M10/0567;H01M4/133;H01M4/525;H01M4/505;H01M4/587;H01M10/0568;H01M4/66;H01M10/0525;H01M10/0585;H01M2/02;H01M10/0569;H01M4/131;H01M4/62 主分类号 H01M10/0567
代理机构 代理人
主权项 1. An addition composition for an electrolytic solution comprising: (a) a silyl group-containing compound (A), wherein at least one hydrogen atom of an acid selected from the group consisting of a protonic acid having phosphorus atom and/or boron atom, a sulfonic acid, and a carboxylic acid is substituted with a silyl group represented by following general formula (A1):[wherein, Ra1, Ra2, and Ra3 each independently represent a hydrocarbon group having 1 to 20 carbon atoms, which may be substituted]; and (b) at least one basic compound (B) selected from the group consisting of a Lewis base and a compound represented by general formula Q+Y− [wherein, Q+ represents a quaternary ammonium group, a quaternary phosphonium group, an alkali metal, or an alkaline earth metal, and Y− represents an alkoxy group, or an aryloxy group.], and/or at least one silicon compound (C) represented by following general formula (C):[wherein, Rc1, Rc2, and Rc3 each independently represent a hydrocarbon group having 1 to 20 carbon atoms, which may be substituted, or an alkoxy group having 1 to 20 carbon atoms, which may be substituted, and X1 is a group represented by general formula OR1 (wherein, R1 represents a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms, which may be substituted, a silyl group having 1 to 20 carbon atoms, SO2CH3, or SO2CF3.), or a halogen atom.]; and wherein the addition composition contains 1 ppm by mass or more and 100% by mass or less of the basic compound (B) and/or the silicon compound (C), relative to 100% by mass of the silyl group-containing compound (A).
地址 Tokyo JP