发明名称 SYNTHESIS METHODS FOR HALOSILANES
摘要 Disclosed are methods of selectively synthesizing inorganic silanes, such as halosilane and dihalosilane, comprising the step of reacting the halide or halogen (i.e., HX or X2 wherein X is Cl, Br, or I) with RSiH3, wherein R is an unsaturated C4 to C8 cyclic hydrocarbon or heterocycle group, provided that a C6 cyclic aromatic includes at least one hydrocarbyl ligand, in the presence of a catalyst, to produce RH and the inorganic silane having the formula SixHaXb, wherein x=1-4; a=1-9; b=1-9; and a+b=2x+2.
申请公布号 US2016264426(A1) 申请公布日期 2016.09.15
申请号 US201615159454 申请日期 2016.05.19
申请人 Air Liquide Advanced Materials, Inc. ;L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude 发明人 KERRIGAN Sean;WAN Zhiwen;GIRARD Jean-Marc
分类号 C01B33/107 主分类号 C01B33/107
代理机构 代理人
主权项 1. A method of synthesizing an inorganic silane having the formula SixHaXb, wherein X=Cl, Br, or I; x=1 to 4; a=1 to 9; b =1 to 9; and a+b=2x+2; the method comprising: mixing a halide reactant having the formula HX or a halogen reactant having the formula X2 with a silane reactant having the formula: SixHyRz wherein y=1 to 9; z=1 to 9; and y+z=2x+2; and R is an unsaturated C4 to C8 cyclic hydrocarbon or heterocycle group, provided that a C6 cyclic aromatic includes at least one hydrocarbyl ligand to produce the inorganic silane and RH reaction product mixture.
地址 Branchburg NJ US