New MOF-type Layered Coordination Polymers Of Manganese, Method Of Their Preparation, Modification And Use Thereof

摘要

The invention solves the problem of the development of microporous layered MOF-type manganese materials based on isonicotinate anions, their synthesis and modification with selected ionic substances and application associated with the adsorption of the molecules and the construction of solid superionic conductors.

主权项

1. New layered MOF-type coordination polymers of manganese defined by the general formula 1:
{[Mn2(ina)4(L)x].yS}n in which:
ina is an isonicotinic acid anion; L is a neutral molecule of a solvent selected from the group consisting of C1-C12 alcohols or water; S independently denotes inert solvent molecule selected from the group consisting of C1-C12 alcohols or water; x varies from 0 to 2; y Independently varies in the range from 0 to 4; n denotes a polymeric structure of the compound.