发明名称 |
Process for liquid-phase oxidation of m-diisopropylbenzene |
摘要 |
A process for producing m-diisopropylbenzene dihydroperoxide which comprises oxidizing m-diisopropylbenzene in the liquid phase with molecular oxygen under alkaline conditions; wherein the oxidation is carried out under conditions (A), (B) and (C) below, (A) under conditions which meet (i), (ii), (iii) and (iv) below, (i) 0</=x</=140 (ii) y>/=80 (iii) -0.05x+110>/=y>/=-0.15x+95 wherein 0</=x</=100 (iv) y</=-0.25x+130 wherein 100<x</=140 in which x represents the absolute value of the concentration of hydroperoxides in the oxidation product in % by weight calculated as m-diisopropylbenzene monohydroperoxide, and y represents the absolute value of the reaction temperature in degrees centigrade, (B) until x reaches at least 120, and (C) so that the reaction temperature at 100<x</=140 is lower than the reaction temperature at the start of the reaction (x=0).
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申请公布号 |
US4237319(A) |
申请公布日期 |
1980.12.02 |
申请号 |
US19780954072 |
申请日期 |
1978.10.24 |
申请人 |
MITSUI PETROCHEMICAL INDUSTRIES LTD. |
发明人 |
NAMBU, HIROHIKO;HASHIMOTO, ISAO;IMAI, ICHIRO |
分类号 |
C07C37/08;C07C;C07C27/00;C07C39/08;C07C67/00;C07C407/00;C07C409/08;C07C409/12;(IPC1-7):C07C179/03 |
主分类号 |
C07C37/08 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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