| 发明名称 |
METHOD OF SYNTHESIS OF 1-ETHYL-2,3-FULLERENEALUMINOCYCLO- -PENTANES |
| 摘要 |
FIELD: chemistry of organometallic compounds. SUBSTANCE: invention relates to a method of synthesis of the new organoaluminium compound of the formula (I) <EMI ID=0.457 HE=30 WI=27 TI=CHI> where n = 1-7; C<SB>60</SB> - the new allotropic modification of carbon that can be used in the fine organic and organometallic synthesis. Method involves an interaction of fullerene (allotropic modification of carbon) with an excess of triethylaluminium at mole ratio = 1: (50-350) in the presence of zirconacene dichloride as a catalyst and a solvent in argon atmosphere, under normal conditions for 24-48 h. The yield of the end product is 56-78%. EFFECT: new compound indicated above, increased yield. 1 cl, 1 tbl, 7 ex
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| 申请公布号 |
RU2132332(C1) |
申请公布日期 |
1999.06.27 |
| 申请号 |
RU19970106736 |
申请日期 |
1997.04.24 |
| 申请人 |
INSTITUT NEFTEKHIMII I KATALIZA S OPYTNYM ZAVODOM;AN RB |
发明人 |
DZHEMILEV U.M.;IBRAGIMOV A.G.;JUSUPOV Z.A.;AKHMETOV M.F.;KHALILOV L.M.;CHEGODAEVA M.F. |
| 分类号 |
C07F5/06;(IPC1-7):C07F5/06 |
主分类号 |
C07F5/06 |
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